Highly selective reduction of biomass-derived furfural by tailoring the microenvironment of Rh@BEA catalysts

被引:12
作者
Zhang, Yuyan [1 ]
Li, Ang [1 ]
Kubu, Martin [1 ]
Shamzhy, Mariya [1 ]
Cejka, Jiri [1 ]
机构
[1] Charles Univ Prague, Fac Sci, Dept Phys & Macromol Chem, Hlavova 2030-8, Prague 12843, Czech Republic
关键词
Rh@BEA; Charge-balancing cations; Furfural; Furfuryl alcohol; 2-methylfuran; LIQUID-PHASE HYDROGENATION; LIGNOCELLULOSIC BIOMASS; ZEOLITE CRYSTALS; ALCOHOL; EFFICIENT; METAL; ACID; 2-METHYLFURAN; NANOPARTICLES; CONVERSION;
D O I
10.1016/j.cattod.2021.09.031
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Furfural is a renewable lignocellulose-derived platform molecule, which can be transformed into biofuels and value-added chemicals (e.g., furfuryl alcohol and 2-methylfuran over metal-supported catalysts). Despite a number of approaches proposed for designing hydrogenation catalysts, highly selective furfural hydrogenation towards furfuryl alcohol (FA) or 2-methylfuran (2-MF) is still challenging. Here, we report on selective trans-formation of furfural either to FA or 2-MF achieved over zeolite BEA-supported Rh catalysts by optimizing Si/Al ratio and charge-balancing cations of the support. Among studied H-and Na-exchanged aluminosilicate BEA zeolite supports (Si/Al = 12.5; 25; 68; 150), Rh@Na-BEA catalysts lacking Bronsted and strong Lewis acidity showed enhanced selectivity towards FA (75 - 94% depending on the Si/Al ratio) at 74 - 84% conversion of furfural. In turn, selective formation of 2-MF (98% selectivity at 87% conversion) was observed over Al-rich Rh@H-BEA catalyst (Si/Al=12.5) with the highest concentration of Bronsted acid sites. Weaker adsorption of FA on Na-vs. H-form of Rh@BEA-12.5 catalyst was verified by FTIR spectroscopy and is assumed a key factor governing selective hydrogenation of furfural to FA over Rh@Na-BEA catalysts.
引用
收藏
页码:295 / 305
页数:11
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