Synthesis of isotactic poly(N-isopropylacrylamide) by RAFT polymerization in the presence of Lewis acid

被引：185
作者：
Ray, B
Isobe, Y
Morioka, K
Habaue, S
Okamoto, Y [1 ]
Kamigaito, M
Sawamoto, M
机构：
[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan
[2] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Kyoto 6068501, Japan
来源：
MACROMOLECULES | 2003年 / 36卷 / 03期
关键词：
D O I：
10.1021/ma0257595
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The synthesis of poly(N-isopropylacrylamide) using reversible addition-fragmentation chain transfer (RAFT) polymerization was presented. RAFT polymerization presented a method wherein isotacticity and molecular weight of the synthesized polymer could be controlled simultaneously in the presence of Lewis acids. The procedure could be extended to the synthesis of the stereo-block homopolymer with different tacticity or block copolymer with another monomer having predetermined chain lengths.
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收藏
页码：543 / 545
页数：3
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