The absolute stereochemistry of cascarillic acid

被引:13
|
作者
Roberts, IO [1 ]
Baird, MS [1 ]
Liu, Y [1 ]
机构
[1] Univ Wales, Dept Chem, Bangor LL57 2UW, Gwynedd, Wales
关键词
cascarillic acid; CPFA; cyclopropane;
D O I
10.1016/j.tetlet.2004.09.141
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
((1S,2R)-2-Hexylcycloprop-1-yl)acetic acid has been synthesised from cis-1,2-dihydroxymethylcyclopropane and shown to be identical to cascarillic acid obtained from cascarilla essential oil. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:8685 / 8686
页数:2
相关论文
共 50 条
  • [21] Asymmetric synthesis of a phosphonic analogue of (-)-allo-norcoronamic acid
    Hercouet, A
    Le Corre, M
    Carboni, B
    TETRAHEDRON LETTERS, 2000, 41 (02) : 197 - 199
  • [22] SYNTHESIS AND ESTABLISHMENT OF THE STRUCTURE OF VINYL ETHER OF MONOSUBSTITUTED CYCLOPROPANECARBOXYLIC ACID
    Shahnazarli, Rita Z.
    PROCESSES OF PETROCHEMISTRY AND OIL REFINING, 2025, 26 (01): : 107 - 113
  • [23] Synthesis of Cyclopropane Derivatives of Aspartic Acid by Thermal Decomposition of Substituted Pyrazolines
    N. A. Anisimova
    G. A. Berkova
    T. Ya. Paperno
    L. I. Deiko
    Russian Journal of General Chemistry, 2002, 72 : 460 - 463
  • [24] Regioselective addition of cyclic nitrones to Feist's acid dimethyl ester
    Molchanov, A. P.
    Tran, T. Q.
    Kostikov, R. R.
    RUSSIAN CHEMICAL BULLETIN, 2011, 60 (11) : 2296 - 2300
  • [25] Stereoselective Synthesis of Cyclopropylidene Iminolactones and Functionalized Cyclopropanecarboxamides Mediated by Triflic Acid
    Maximiano, Adrielle P.
    Sa, Marcus M.
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2019, 2019 (38) : 6515 - 6524
  • [26] 1,1-Dihalo-2-benzycyclopropanes in reaction with nitrous acid
    A. Z. Kadzhaeva
    E. V. Trofimova
    R. A. Gazzaeva
    A. N. Fedotov
    S. S. Mochalov
    Moscow University Chemistry Bulletin, 2009, 64 (1) : 28 - 31
  • [27] Synthesis of cyclopropane derivatives of aspartic acid by thermal decomposition of substituted pyrazolines
    Anisimova, NA
    Berkova, GA
    Paperno, TY
    Deiko, LI
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2002, 72 (03) : 460 - 463
  • [28] Esters of dichloroacetic acid in the synthesis of fullerene C60 functionalized methane derivatives
    S. A. Torosyan
    F. A. Gimalova
    Yu. N. Biglova
    V. V. Mikheev
    M. S. Miftakhov
    Russian Journal of Organic Chemistry, 2012, 48 : 736 - 738
  • [29] Transition metal or Lewis acid-catalyzed asymmetric reactions with chiral organosulfur functionality
    Hiroi, K
    REVIEWS ON HETEROATOM CHEMISTRY, 1996, 14 : 21 - 57
  • [30] Reaction of cyclopropane carboxylic acid derivatives with sulphur tetrafluoride - an example of a diastereoselective ring opening
    Hell, Z
    Finta, Z
    Dmowski, W
    Faigl, F
    Pustovit, YM
    Toke, L
    Harmat, V
    JOURNAL OF FLUORINE CHEMISTRY, 2000, 104 (02) : 297 - 301