Hydrogenation of silyl formates: sustainable production of silanol and methanol from hydrosilane and carbon dioxide

被引：15

作者：

Koo, Jangwoo ^{[1
]}

Kim, Seung Hyo ^{[1
]}

Hong, Soon Hyeok ^{[1
]}

机构：

[1] Seoul Natl Univ, Coll Nat Sci, Dept Chem, 1 Gwanak Ro, Seoul 08826, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 39期

基金：

新加坡国家研究基金会;

关键词：

N-HETEROCYCLIC CARBENE; FORMIC-ACID; CATALYTIC HYDROSILYLATION; EFFICIENT HYDROGENATION; CO2; OXIDATION; AMINES; DISPROPORTIONATION; CONVERSION; CHEMISTRY;

D O I：

10.1039/c8cc02276c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new process for simultaneously obtaining two chemical building blocks, methanol and silanol, was realized starting from silyl formates which can be derived from silane and carbon dioxide. Understanding the reaction mechanism enabled us to improve the reaction efficiency by the addition of a small amount of methanol.

引用

页码：4995 / 4998

页数：4

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