Synthesis, structure and reductive dechlorination of the C-centred phosphorus(III) b-diketiminate PCl(Ph)L [L = C{C(Me)NC6H3Pri2-2,6}{C(Me)NHC6H3Pri2-2,6}]

被引：41

作者：

Hitchcock, PB ^{[1
]}

Lappert, MF ^{[1
]}

Nycz, JE ^{[1
]}

机构：

[1] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 10期

关键词：

D O I：

10.1039/b301294h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of the beta-diketimine HL with successively LiBun and PCl2Ph gave the first C-centered monodentate beta-diketiminate PCl(Ph) L 1; with C8K 1 underwent reductive dechlorination yielding 2, a novel N-P-III-P-III-C=C heterocycle.

引用

页码：1142 / 1143

页数：2

共 21 条

[1] High-activity, single-site catalysts for the alternating copolymerization of CO2 and propylene oxide [J].

Allen, SD ;

Moore, DR ;

Lobkovsky, EB ;

Coates, GW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (48) :14284-14285

[2] Unusual crystalline heterobimetallic trinuclear β-diketiminates [Yb{L(μ-Li(thf)}2] and [Yb{L′(μ-Li(thf)}2]• thf [L, L′ = {N(SiMe3)C(R)}2CH, R = Ph, C6H4Ph-4] [J].

Avent, AG ;

Khvostov, AV ;

Hitchcock, PB ;

Lappert, MF .

CHEMICAL COMMUNICATIONS, 2002, (13) :1410-1411

[3]

Batsanov AS, 2001, EUR J INORG CHEM, P1729

[4] The chemistry of β-diketiminatometal complexes [J].

Bourget-Merle, L ;

Lappert, MF ;

Severn, JR .

CHEMICAL REVIEWS, 2002, 102 (09) :3031-3065

[5] Electrophilic metal precursors and a beta-diimine ligand for nickel(II)- and palladium(II)-catalyzed ethylene polymerizations [J].

Feldman, J ;

McLain, SJ ;

Parthasarathy, A ;

Marshall, WJ ;

Calabrese, JC ;

Arthur, SD .

ORGANOMETALLICS, 1997, 16 (08) :1514-1516

[6] A well-defined iron(II) alkoxide initiator for the controlled polymerisation of lactide [J].

Gibson, VC ;

Marshall, EL ;

Navarro-Llobet, D ;

White, AJP ;

Williams, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (23) :4321-4322

[7]

Hardman NJ, 2001, ANGEW CHEM INT EDIT, V40, P2172, DOI 10.1002/1521-3773(20010601)40:11<2172::AID-ANIE2172>3.0.CO

[8]

2-Y

[9] Spontaneous generation of stable pnictinyl radicals from "jack-in-the-box" dipnictines: A solid-state, gas-phase, and theoretical investigation of the origins of steric stabilization [J].

Hinchley, SL ;

Morrison, CA ;

Rankin, DWH ;

Macdonald, CLB ;

Wiacek, RJ ;

Voigt, A ;

Cowley, AH ;

Lappert, MF ;

Gundersen, G ;

Clyburne, JAC ;

Power, PP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (37) :9045-9053

[10] The role of lithium 1,3-bis(trimethylsilyl)-1-aza-allyls in phosphorus chemistry (vol 529, pg 243, 1997) [J].

Hitchcock, PB ;

Lappert, MF ;

Layh, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 580 (02) :385-398

← 1 2 3 →