Electrochemical and 119Sn Mossbauer study of sulfospinels as anode materials for lithium-ion batteries

被引：9
|
作者：
Dedryvère, R
Olivier-Fourcade, J
Jumas, JC
Denis, S
Lavela, P
Tirado, JL
机构：
[1] Univ Montpellier 2, UMR 5072 CNRS, Lab Agregats Mol & Mat Inorgan, F-34095 Montpellier, France
[2] UPRESA A 6007 CNRS, Lab React & Chim Solides, F-80039 Amiens, France
[3] Univ Cordoba, Fac Ciencias, Lab Quim Inorgan, E-14004 Cordoba, Spain
来源：
ELECTROCHIMICA ACTA | 2000年 / 46卷 / 01期
关键词：
spinel sulfides; lithium-ion; Mossbauer spectroscopy; anode materials; cycling properties;
D O I：
10.1016/S0013-4686(00)00564-8
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Sn-119 Mossbauer spectroscopy, X-ray diffraction and electrochemical experiments were carried out to characterize the reaction mechanism of lithium with spinel phases of the Cu2S-In2S3-SnS2 system. This analysis reveals an irreversible part of the mechanism linked to the reduction of the cations involving a spinel to rocksalt transformation followed by a structural breakdown, and a reversible part linked to the formation of lithium-metal alloys. The electrochemical investigation has shown interesting reversible capacities for these materials, and their possible use as anode materials in lithium-ion cells. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：127 / 135
页数：9
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