Atmospheric chemistry of CF3CF=CH2:: Kinetics and mechanisms of gas-phase reactions with Cl atoms, OH radicals, and O3

被引：211
作者：
Nielsen, O. J.
Javadi, M. S.
Sulbaek Andersen, M. P.
Hurley, M. D.
Wallington, T. J.
Singh, R.
机构：
[1] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen, Denmark
[2] Ford Motor Co, Phys & Environm Sci Dept, Dearborn, MI 48121 USA
[3] Honeywell Int Inc, Morristown, NJ 07962 USA
来源：
CHEMICAL PHYSICS LETTERS | 2007年 / 439卷 / 1-3期
关键词：
D O I：
10.1016/j.cplett.2007.03.053
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Long path length FTIR-smog chamber techniques were used to determine k(Cl + CF3CF=CH2) = (7.03 +/- 0.59) x 10(-11) k(OH + CF3CF=CH2) = (1.05 +/- 0.17) x 10(-12), and k(O-3 + CF3CF=CH2) = (2.77 +/- 0.21) x 10(-21) cm(3) molecule' s(-1) in 700 Torr of N-2, N-2/O-2, or air diluent at 296 K. CF3CF=CH2 has an atmospheric lifetime of approximately 11 days and a global warming potential (100 yr time horizon) of four. CF3CF=CH2 has a negligible global warming potential and will not make any significant contribution to radiative forcing of climate change. (c) 2007 Elsevier B.V. All rights reserved.
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页码：18 / 22
页数：5
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