Synthesis and Characterization of a New N"-[(1Z,2E)-2-(Hydroxyimino)-1-phenylpropylidene]-N"′-[(1E)-phenylmethylene]thiocarbonohydrazide and its Complexes with Co(II), Ni(II) and Cu(II)

被引：0
作者：
Sawant, Dilip C. [1 ]
Venkatchallam, A. [1 ]
Deshmukh, R. G. [1 ]
机构：
[1] Bhavans Coll, Dept PG Studies & Res Chem, Bombay 58, Maharashtra, India
来源：
E-JOURNAL OF CHEMISTRY | 2010年 / 7卷 / 02期
关键词：
Isonitrosopropiophenone; Thiocarbohydrazide; Benzaldehyde; Low spin octahedral geometry; Copper-copper interaction; TRANSITION-METAL-COMPLEXES; SCHIFF-BASE LIGAND; PALLADIUM(II) COMPLEXES; MICROSCOPIC CRYSTALS; COPPER(II); NICKEL(II); COBALT(II); THIOSEMICARBAZONES; MANGANESE(II);
D O I：
10.1155/2010/525197
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Synthesis and characterization of a new N''-[(1Z,2E)-2-(hydroxyimino) -1-phenylpropylidene]-N'''-[(1E)-phenylmethylene]-thiocarbonohydrazide and its metal complexes with Co(II), Ni(II) and Cu(II) metal ions. The ligand synthesis and characterization is reported for first time. The complexes of divalent metal ions were synthesized in 1: 2 molar proportion using ethanol as solvent. The ligands as well as its metal complexes were characterized using various physicochemical techniques such as elemental analysis, spectral and magnetic measurements and electrical conductivity measurements in case of the metal complexes only. The data for the metal complexes reveals that they may be represented by ML2. The metal complexes show interesting features of coordination structure.
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收藏
页码：409 / 418
页数：10
相关论文
共 40 条
[1]   Bimetallic complexes of Schiff base bis-[4-hydroxycuomarin-3-yl]-1N,5N-thiocarbohydrazone as a potentially dibasic pentadentate ligand.: Synthesis, spectral, and antimicrobial properties [J].
Abou-Melha, K. S. ;
Faruk, H. .
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2008, 5 (01) :122-134
[2]   Manganese(II) and palladium(II) complexes containing a new macrocyclic Schiff base ligand: antibacterial properties [J].
Anacona, JR ;
Bastardo, E ;
Camus, J .
TRANSITION METAL CHEMISTRY, 1999, 24 (04) :478-480
[3]  
AUDRIETH LF, 1955, CHEM ABSTR
[4]   Synthetic and spectroscopic investigations of N(4)-substituted isatin thiosemicarbazones and their copper(II) complexes [J].
Bain, GA ;
West, DX ;
Krejci, J ;
ValdesMartinez, J ;
HernandezOrtega, S ;
Toscano, RA .
POLYHEDRON, 1997, 16 (05) :855-862
[5]  
BANERJA D, 1994, COORDINATION CHEM
[6]  
BANERJEA D, 1968, INDIAN J CHEM, V6, P34
[7]  
CHAKRABARTI J, 1981, INDIAN J CHEM A, V20, P431
[8]   STRUCTURAL CHEMISTRY OF TRANSITION-METAL COMPLEXES OF OXIMES [J].
CHAKRAVORTY, A .
COORDINATION CHEMISTRY REVIEWS, 1974, 13 (01) :1-46
[9]   Chromium(III), manganese(II), cobalt(II), nickel(II), copper(II) and palladium(II) complexes of a 12-membered tetraaza [N4] macrocyclic ligand [J].
Chandra, S ;
Sharma, SD .
TRANSITION METAL CHEMISTRY, 2002, 27 (07) :732-735
[10]  
Demir I, 2008, ACTA CHIM SLOV, V55, P120
1234