The study of the reaction between thiophosphoryl esters and boron tribromide. The synthesis of oxathiaphosphaboretanes

被引：0

作者：

Lewkowski, J

Mortier, J

Vaultier, M

机构：

[1] Univ Lodz, Dept Organ Chem, PL-90136 Lodz, Poland

[2] Univ Rennes 1, CNRS, UMR 6510, F-35042 Rennes, France

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2000年 / 162卷

关键词：

thiophosphoryl compounds; boron tribromide; oxathiaphosphaboretanes; NMR studies; mechanism;

D O I：

10.1080/10426500008045215

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions between three thiophosphoryl esters and boron tribromide are reported. O,O,O-triethyl phosphorothionate (1) and O,O-diethyl methanephosphonothionate (5) gave substituted oxathiaphosphaboretanes 4 and 7 respectively. O-methyl diphenyl-phosphinothionate (9) led to the complex 11 and the corresponding oxarhiaphosphaboretane 12. In order to establish the mechanism, reactions were monitored by the multinuclear NMR spectroscopy.

引用

页码：1 / 14

页数：14

共 17 条

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