Vapor-liquid equilibria for the systems difluoromethane plus hydrogen fluoride, dichlorodifluoromethane plus hydrogen fluoride, and chlorine plus hydrogen fluoride

被引:4
作者
Kang, YW [1 ]
机构
[1] KIST, Div Environm & CFC Technol, Seoul, South Korea
关键词
D O I
10.1021/je970142h
中图分类号
O414.1 [热力学];
学科分类号
摘要
Isothermal vapor-liquid equilibria for difluoromethane + hydrogen fluoride, dichlorodifluoromethane + hydrogen fluoride, and chlorine + hydrogen fluoride have been measured. The experimental data for the binary systems are correlated with the NRTL equation with the vapor-phase association model for the mixtures containing hydrogen fluoride, and the relevant parameters are presented. The binary system difluoromethane + hydrogen fluoride forms a homogeneous liquid phase, and the others form minimum boiling heterogeneous azeotropes at the experimental conditions.
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页码:13 / 16
页数:4
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