Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters

被引：646
作者：
Zeng, Xing-Ping [1 ]
Cao, Zhong-Yan [1 ]
Wang, Yu-Hui [1 ]
Zhou, Feng [1 ]
Zhou, Jian [1 ,2 ,3 ]
机构：
[1] E China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
[2] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
[3] Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China
来源：
CHEMICAL REVIEWS | 2016年 / 116卷 / 12期
关键词：
C-C BOND; ASYMMETRIC TOTAL-SYNTHESIS; TRICYCLIC BETA-LACTONES; STEREOGENIC CENTER; WIELAND-MIESCHER; H ARYLATION; AMINO-ACID; INTERMOLECULAR DESYMMETRIZATION; POLYCYCLIC DERIVATIVES; EFFICIENT CONSTRUCTION;
D O I：
10.1021/acs.chemrev.6b00094
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This Review summarizes the advances in the construction of all-carbon quaternary stereocenters via catalytic enantioselective desymmetrization of prochiral and mesa-compounds, highlights the power and potential of this strategy in the total synthesis of natural products and biologically active compounds, and outlines the synthetic opportunities still available.
引用
收藏
页码：7330 / 7396
页数：67
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