Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters

被引：646

作者：

Zeng, Xing-Ping ^{[1
]}

Cao, Zhong-Yan ^{[1
]}

Wang, Yu-Hui ^{[1
]}

Zhou, Feng ^{[1
]}

Zhou, Jian ^{[1
,2
,3
]}

机构：

[1] E China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

[2] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China

[3] Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

CHEMICAL REVIEWS | 2016年 / 116卷 / 12期

关键词：

C-C BOND; ASYMMETRIC TOTAL-SYNTHESIS; TRICYCLIC BETA-LACTONES; STEREOGENIC CENTER; WIELAND-MIESCHER; H ARYLATION; AMINO-ACID; INTERMOLECULAR DESYMMETRIZATION; POLYCYCLIC DERIVATIVES; EFFICIENT CONSTRUCTION;

D O I：

10.1021/acs.chemrev.6b00094

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This Review summarizes the advances in the construction of all-carbon quaternary stereocenters via catalytic enantioselective desymmetrization of prochiral and mesa-compounds, highlights the power and potential of this strategy in the total synthesis of natural products and biologically active compounds, and outlines the synthetic opportunities still available.

引用

页码：7330 / 7396

页数：67

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