Liquid-Liquid Equilibria for the Ternary Systems Dodecane plus Toluene or Thiophene or Pyridine+1-Ethyl-3-methylimidazolium Methyl Sulfate

被引：17
作者：
Baelhadj, Abdelaziz Chikh [1 ,2 ]
Mutelet, Fabrice [2 ]
机构：
[1] USTHB, Fac Chim, Lab Thermodynam & Modelisat Mol, BP 32 El Alia, Bab Ezzouar 16111, Alger, Algeria
[2] Univ Lorraine, Ecole Natl Super Ind Chim, Lab React & Genie Procedes, UMR 7274,CNRS, 1 Rue Grandville, F-54000 Nancy, France
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2017年 / 62卷 / 06期
关键词：
IONIC LIQUIDS; ACTIVITY-COEFFICIENTS; INFINITE DILUTION; ORGANIC-COMPOUNDS; EXTRACTIVE DESULFURIZATION; ALIPHATIC-HYDROCARBONS; THERMODYNAMIC PROPERTIES; PHASE-DIAGRAMS; BINARY-SYSTEMS; FUEL OILS;
D O I：
10.1021/acs.jced.6b00437
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Liquid liquid equilibria for the three ternary systems (dodecane + toluene + 1-ethyl-3-methylimidazolium methyl sulfate ([EMIM][MeSQ(4)])), (dodecane + thiophene + [EMIM][MeSO4]) and (dodecane + pyridine + [EMIM][MeSO4]) were measured at 298.15 K and at atmospheric pressure. Experimental data were used to calculate the distribution coefficient and selectivity values. Results indicate that [EMIM] [MeSO4] is a potential solvent for the extraction of pyridine from n-dodecane. It was found that NTRL and UNIQUAC models can used to represent with good accuracy ternary systems containing [EMIM][MeSO4]. Then, we have shown that [EMIM] [MeSO4] can be used as solvent for the extraction of pyridine from a synthetic mixture.
引用
收藏
页码：1749 / 1755
页数：7
相关论文
共 59 条
[1]   STATISTICAL THERMODYNAMICS OF LIQUID-MIXTURES - NEW EXPRESSION FOR EXCESS GIBBS ENERGY OF PARTLY OR COMPLETELY MISCIBLE SYSTEMS [J].
ABRAMS, DS ;
PRAUSNITZ, JM .
AICHE JOURNAL, 1975, 21 (01) :116-128
[2]   Activity Coefficients at Infinite Dilution for Organic Compounds Dissolved in 1-Alkyl-1-methylpyrrolidinium Bis(trifluoromethylsulfonyl)imide Ionic Liquids Having Six-, Eight-, and Ten-Carbon Alkyl Chains [J].
Acree, William E., Jr. ;
Baker, Gary A. ;
Revelli, Anne-Laure ;
Moise, Jean-Charles ;
Mutelet, Fabrice .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2012, 57 (12) :3510-3518
[3]   Study on the separation of propylbenzene from alkanes using two methylsulfate-based ionic liquids at (313 and 333) K [J].
Al-Jimaz, Adel S. ;
Alkhaldi, Khaled H. A. E. ;
Al-Rashed, Mohsen H. ;
Fandary, Mohamed S. ;
AlTuwaim, Mohammad S. .
FLUID PHASE EQUILIBRIA, 2013, 354 :29-37
[4]   Thiophene separation from aliphatic hydrocarbons using the 1-ethyl-3-methylimidazolium ethylsulfate ionic liquid [J].
Alonso, Luisa ;
Arce, Alberto ;
Francisco, Maria ;
Soto, Ana .
FLUID PHASE EQUILIBRIA, 2008, 270 (1-2) :97-102
[5]   Liquid-liquid equilibria of ([C2mim][EtSO4] plus thiophene plus 2,2,4-trimethylpentane) and ([C2mim][EtSO4] plus thiophene plus toluene):: Experimental data and correlation [J].
Alonso, Luisa ;
Arce, Alberto ;
Francisco, Maria ;
Soto, Ana .
JOURNAL OF SOLUTION CHEMISTRY, 2008, 37 (10) :1355-1363
[6]   Liquid-liquid equilibria for systems composed by 1-methyl-3-octylimidazolium tetrafluoroborate ionic liquid, thiophene, and n-hexane or cyclohexane [J].
Alonso, Luisa ;
Arce, Alberto ;
Francisco, Maria ;
Rodriguez, Oscar ;
Soto, Ana .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (05) :1729-1732
[7]   Extraction Ability of Nitrogen-Containing Compounds Involved in the Desulfurization of Fuels by Using Ionic Liquids [J].
Alonso, Luisa ;
Arce, Alberto ;
Francisco, Maria ;
Soto, Ana .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (09) :3262-3267
[8]   COSMO-RS-Based Screening of Ionic Liquids as Green Solvents in Denitrification Studies [J].
Anantharaj, R. ;
Banerjee, Tamal .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (18) :8705-8725
[9]   1-Ethyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl}amide as solvent for the separation of aromatic and aliphatic hydrocarbons by liquid extraction - extension to C7- and C8-fractions [J].
Arce, Alberto ;
Earle, Martyn J. ;
Rodriguez, Hector ;
Seddon, Kennet R. ;
Soto, Ana .
GREEN CHEMISTRY, 2008, 10 (12) :1294-1300
[10]   Extractive denitrogenation of fuel oils with dicyanamide-based ionic liquids [J].
Asumana, Charles ;
Yu, Guangren ;
Guan, Yanwen ;
Yang, Shendu ;
Zhou, Shaozhen ;
Chen, Xiaochun .
GREEN CHEMISTRY, 2011, 13 (11) :3300-3305
123456