Synthesis of Polycyclic Dihydroindoles by Selective Decomposition of Bis(1,2,3-triazoles) Mediated by Rhodium Catalysis

被引：13

作者：

Jana, Sampad ^{[1
]}

Vroemans, Robby ^{[1
]}

Dehaen, Wim ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Dept Chem, Mol Design & Synth, Celestijnenlaan 200F, B-3001 Leuven, Belgium

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2017年 / 359卷 / 18期

关键词：

azavinylcarbenes; click chemistry; rhodium(II) catalysis; triazoles; AZAVINYL CARBENES; 1,2,3-TRIAZOLES; ANNULATION; N-SULFONYL-1,2,3-TRIAZOLES; PYRROLES; INDOLES; RINGS; NH-1,2,3-TRIAZOLES; REARRANGEMENT; DERIVATIVES;

D O I：

10.1002/adsc.201700756

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

We report the selective decomposition of bis(1,2,3-triazoles) under rhodium(II) catalysis. The bis(1,2,3-triazoles) undergo an intramolecular transannulation reaction via an azavinylcarbene intermediate, resulting in the formation of polycyclic dihydroindoles containg a fused triazole ring.

引用

页码：3085 / 3089

页数：5

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