Pathway-dependent gold nanoparticle formation by biocatalytic self-assembly

被引:19
作者
Sahoo, Jugal Kishore [1 ,6 ]
Roy, Sangita [1 ]
Javid, Nadeem [1 ,2 ]
Duncan, Krystyna [1 ]
Aitken, Lynsey [1 ]
Ulijn, Rein V. [3 ,4 ,5 ,7 ,8 ]
机构
[1] Univ Strathclyde, WestCHEM, Dept Pure & Appl Chem, Technol & Innovat Ctr, Glasgow G1 1RD, Lanark, Scotland
[2] Univ Bradford, Sch Chem & Biosci, Bradford, W Yorkshire, England
[3] CUNY, Adv Sci Res Ctr, Grad Ctr, 85 St Nicholas Terrace, New York, NY 10031 USA
[4] CUNY, Grad Ctr, Biochem Chem & Phys, New York, NY 10016 USA
[5] CUNY, Hunter Coll, Dept Chem, 695 Pk Ave, New York, NY 10065 USA
[6] Univ Notre Dame, Dept Chem & Biomol Engn, McCourtney Hall, Notre Dame, IN 46556 USA
[7] CUNY, ASRC, New York, NY 10031 USA
[8] CUNY, Hunter Coll, New York, NY 10031 USA
基金
英国生物技术与生命科学研究理事会; 欧洲研究理事会;
关键词
SUPRAMOLECULAR SYSTEMS; SILVER NANOPARTICLES; BIOMIMETIC SYNTHESIS; PEPTIDE AMPHIPHILES; HYDROGELS; NANOSTRUCTURES; REDUCTION; TEMPLATES; DESIGN; MATTER;
D O I
10.1039/c7nr04624c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report on the use of non-equillibrium biocatalytic self-assembly and gelation to guide the reductive synthesis of gold nanoparticles. We show that biocatalytic rates simultaneously dictate supramolecular order and presentation of reductive phenols which in turn results in size control of nanoparticles that are formed.
引用
收藏
页码:12330 / 12334
页数:5
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