Novel polymer-based nanoporous carbon adsorbent for removal of pentachlorophenol from water

被引:0
作者
Stoycheva, I. G. [1 ]
Tsyntsarski, B. G. [1 ]
Petrova, B. N. [1 ]
Budinova, T. K. [1 ]
Popova, A. [1 ]
Petrov, N. V. [1 ]
Nagel, B. [2 ]
Szeluga, U. [2 ]
机构
[1] Bulgarian Acad Sci, Inst Organ Chem, Ctr Phytochem, Acad G Bonchev Str,Bl 9, BU-1113 Sofia, Bulgaria
[2] Polish Acad Sci, Ctr Polymer & Carbon Mat, M Sklodowskiej Curie 34, PL-41819 Zabrze, Poland
来源
BULGARIAN CHEMICAL COMMUNICATIONS | 2017年 / 49卷
关键词
Adsorption; activated carbon; pentachlorophenol; water purification; polymer waste; AQUEOUS-SOLUTION; SUPPORTED CATALYSTS; ADSORPTION; SORPTION; DECOMPOSITION; WASTE; IR;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polyolefin material - polyolefin wax, a by-product from industrial production of polyethylene at low pressure - was used for preparation of nanoporous activated carbon. The adsorbent surface characterization revealed well-developed surface area and presence of high amount of surface functional groups, capable of binding the adsorbate molecules. The results suggest a possible use of polymer waste as a suitable precursor for production of nanoporous activated carbon, thus lowering the cost of wastewater treatment processes. The obtained activated carbon was applied for adsorption of pentachlorophenol (PCP) from aqueous solution. Batch adsorbing experiments were performed under different conditions, i.e. concentration of pentachlorophenol, pH, contact time, etc. The adsorption of pentachlorophenol was found to follow Langmuir equation, as well as Freundlich equation.
引用
收藏
页码:44 / 50
页数:7
相关论文
共 25 条
[1]   Pentachlorophenol (PCP) adsorption from aqueous solution by activated carbons prepared from corn wastes [J].
Abdel-Ghani, N. T. ;
El-Chaghaby, G. A. ;
Zahran, E. M. .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY, 2015, 12 (01) :211-222
[2]   Simultaneous removal of aluminum, iron, copper, zinc, and lead from aqueous solution using raw and chemically treated African beech wood sawdust [J].
Abdel-Ghani, Nour T. ;
El-Chaghaby, Ghadir A. ;
Helal, Farag S. .
DESALINATION AND WATER TREATMENT, 2013, 51 (16-18) :3558-3575
[3]  
Bansal RC., 2005, ACTIVATED CARBON ADS, DOI 10.1201/9781420028812
[4]  
Boehm H.P., 1966, CHEM IDENTIFICATION, V16,, P179
[5]   Sorption of pentachlorophenol on pine bark [J].
Brás, I ;
Lemos, L ;
Alves, A ;
Pereira, MFR .
CHEMOSPHERE, 2005, 60 (08) :1095-1102
[6]   Removal of chlorophenols in aqueous solution by carbon black low-cost adsorbents. Equilibrium study and influence of operation conditions [J].
Dominguez-Vargas, Joaquin R. ;
Navarro-Rodriguez, Juan A. ;
Beltran de Heredia, Jesus ;
Cuerda-Correa, Eduardo M. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 169 (1-3) :302-308
[7]   Pentachlorophenol removal from aqueous matrices by sorption with almond shell residues [J].
Estevinho, B. N. ;
Ratola, N. ;
Alves, A. ;
Santos, L. .
JOURNAL OF HAZARDOUS MATERIALS, 2006, 137 (02) :1175-1181
[8]   Removal of 2,4-dichlorophenol and pentachlorophenol from waters by sorption using coal fly ash from a Portuguese thermal power plant [J].
Estevinho, Berta N. ;
Martins, Isabel ;
Ratola, Nuno ;
Alves, Arminda ;
Santos, Lucia .
JOURNAL OF HAZARDOUS MATERIALS, 2007, 143 (1-2) :535-540
[9]  
Giles C., 1960, STUDIES ADSORPTIO 11, P3973
[10]  
Greg S.J., 1982, Adsorption, Surface area and Porosity