Photoactivated Racemization Catalyst for Dynamic Kinetic Resolution of Secondary Alcohols

被引：23

作者：

Do, Youngshil ^{[1
]}

Hwang, In-Chul ^{[1
]}

Kim, Mahn-Joo ^{[1
]}

Park, Jaiwook ^{[1
]}

机构：

[1] Pohang Univ Sci & Technol POSTECH, Dept Chem, Pohang 790784, Kyeongbuk, South Korea

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 75卷 / 16期

关键词：

AMBIENT-TEMPERATURE; ROOM-TEMPERATURE; RUTHENIUM; METAL; COMBINATION; COMPLEXES; ENZYMES;

D O I：

10.1021/jo1009036

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Household fluorescent light activates a diruthenium complex to generate catalytic species highly active for the racemization of secondary alcohols under ambient conditions. This catalyst system is applicable for the chemoenzymatic dynamic kinetic resolution of racemic alcohols to give optically pure acetates under mild conditions.

引用

页码：5740 / 5742

页数：3

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