Antisymmetry and stability of water systems. II. Polyhedral clusters

被引：1

作者：

Kirov, M. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Div, Inst Earth Cryosphere, Tyumen, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2007年 / 48卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

antisymmetry; asymmetry; water; polyhedral cluster; residual entropy; isomorphism; chirality;

D O I：

10.1007/s10947-007-0013-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The generalized symmetry of proton configurations of water polyhedral clusters is studied. A change in the directions of all hydrogen bonds is used as the additional approximate operation of antisymmetry. The dependence of the energy of antisymmetric configurations on the cluster stabilization energy is found. It is concluded that the internal molecular asymmetry of water that is caused by the approximate character of antisymmetry of hydrogen bonding can be of fundamental scientific importance.

引用

页码：88 / 93

页数：6

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