Organophosphorus flame retardants (OPFRs) in the seawater and sediments of the Qinzhou Bay, Northern Beibu Gulf: Occurrence, distribution, and ecological risks

The occurrence, distributions, and ecological risks of 11 organophosphate flame retardants (OPFRs) were investigated in the seawater and sediment samples from the Qinzhou Bay. The sigma 11OPFRs in the surface seawater and sediments ranged from 150 to 885 ng/L and from <the limit of quantification (LOQ) to 32.2 ng/g dw, respectively, with high levels of OPFRs in the industrialized and port areas. Tris (2-chloro-propyl) phosphate (TCIPP), tris (2-chloroethyl) phosphate (TCEP), and tri-n-butyl phosphate (TNBP) were the dominant OPFRs in the surface seawater and sediments. The sigma 11OPFRs concentrations in the sediment core ranged 1.2-18.6 ng/g dw and the vertical trends showed a recent increase of OPFRs emissions, especially for TNBP and triphenyl phosphate (TPHP). Risk assessment revealed that individual OPFR could pose low to medium ecological risks, but the risk from the mixture of OPFRs on aquatic organisms requires more attention.