Transition metal complexes with Girard reagent-based ligands, Part I:: Synthesis and crystal structure of the first cobalt(III) complexes with Schiff base derivative of Girard reagent

被引：26

作者：

Vojinovic, LS

Leovac, VM

Novakovic, SB

Bogdanovic, GA

Csanádi, JJ

Cesljevic, VI

机构：

[1] VINCA Inst Nucl Sci, YU-11001 Belgrade, Serbia And Mont, Serbia

[2] Univ Novi Sad, Fac Sci, Dept Chem, YU-21000 Novi Sad, Serbia And Mont, Serbia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 12期

关键词：

cobalt(III) complexes; pyridoxilidene Girard-T hydrazone; X-ray crystal structure;

D O I：

10.1016/j.inoche.2004.09.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new ligand, pyridoxilidene Girard-T hydrazone, [H3L]Cl-2 . 2H(2)O, and its octahedral cobalt(III) complexes [Co(HL) (NO2)(3)] . H2O (1) and [Co(HL)(2)](PF6)(3) (2) were synthesized. The X-ray analysis of (1) showed that the complex has a mer-octahedral configuration formed by coordination of the tridentate ONO neutral Schiff-base molecule and three monodentate N-bonded NO2 groups. Hydrogen bonds and intermolecular interactions for this complex are discussed. Complex (2) also has a mer-octahedral configuration. The ligand and complexes were characterized by elemental analysis, conductometric and magnetochemical measurements, IR and UV-Visible, H-1 and C-13 NMR spectra. (C) 2004 Published by Elsevier B.V.

引用

页码：1264 / 1268

页数：5

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