Asymmetric hydrogenation of aromatic ketones by chiral (1S,2S)-DPEN-Ru(II)Cl2(TPP)2 encapsulated in SBA-16

被引：7

作者：

Liu, Jianhong ^{[1
,2
,3
]}

Fan, Binbin ^{[1
]}

Liang, Dong ^{[1
]}

Shi, Xiufeng ^{[1
]}

Li, Ruifeng ^{[1
]}

Chen, Hua ^{[3
]}

机构：

[1] Taiyuan Univ Technol, Key Lab Coal Sci & Technol, Minist Educ, Inst Special Chem, Taiyuan 030024, Peoples R China

[2] Shanxi Datong Univ, Coll Chem & Chem Engn, Datong 037009, Peoples R China

[3] Sichuan Univ, Minist Educ, Key Lab Green Chem & Technol, Inst Homogeneous Catalysis,Coll Chem, Chengdu 610064, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2010年 / 11卷 / 05期

关键词：

Asymmetric hydrogenation; Encapsulation; SBA-16; Aromatic ketone; Chiral Ru complex; ENANTIOSELECTIVE HYDROGENATION; IONIC LIQUID; CATALYSTS; RU; ACETOPHENONE; COPOLYMER;

D O I：

10.1016/j.catcom.2009.11.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Chiral complex (1S,2S)-DPEN-RuCl2(TPP)(2) (DPEN = 1,2-diphenylethylenediamine; TPP = triphenylphosphine) was successfully encapsulated in the mesoporous cage of SBA-16 modified with phenyltrimethoxysilane. This was verified by ICP, powder XRD, N-2 adsorption, FTIR, DRS and TEM analysis. The encapsulated chiral Ru complex gave high catalytic activity and excellent enantioselectivity like its homogeneous counterpart in asymmetric hydrogenation of various aromatic ketones. The encapsulated complex also showed high stability and could be recycled without significant loss of activity and enantioselectivity. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：373 / 377

页数：5

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