Synthesized Fe-doping Li3V2(PO4)3/C cathode material from combustion synthesis precursors with enhanced electrochemical performance

被引:6
作者
Cao, Zhiqin [1 ]
Zuo, Chengyang [1 ]
Cui, Xumei [1 ]
Zhang, Xuefeng [1 ]
机构
[1] Panzhihua Univ, Coll Vanadium & Titanium, Panzhihua 617000, Peoples R China
关键词
Solution combustion synthesis; Li3V2(PO4)(3); Cathode; Electrochemical performance; LITHIUM-ION BATTERIES; FACILE ROUTE; LIFE CATHODE; CARBON; COMPOSITES; MECHANISM; NANOFIBER;
D O I
10.1007/s11581-019-03107-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Fe-doping Li3V2(PO4)(3)/C material was successfully synthesized from combustion synthesis precursors. The Li3V2(PO4)(3) is layered by amorphous carbon with a porous structure and doped with Fe, which can improve the Li+ transfer rate and conductivity. The 1% Fe-doped products used as cathode electrode for lithium-ion batteries exhibit enhanced electrochemical performance. In 3.0~4.8 V, it has a specific discharge capacity of 180 mAh g(-1) after 20 cycles at 0.1 C, 142.5 mAh g(-1) after 500 cycles at 1 C, and 132.5 mAh g(-1) after 500 cycles at 10 C. Moreover, it shows stabilized specific discharge capacity of 65.9 mAh g(-1) after 500 cycles at a rate of 20 C, and the capacity retention is 98%. Thus, it could infer the Fe-doping Li3V2(PO4)(3)/C material is a permission candidated material for application in lithium-ion batteries with high performance.
引用
收藏
页码:5709 / 5716
页数:8
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