Y2O3 functionalized natural palygorskite as an adsorbent for methyl blue removal

被引：33
作者：
He, Xi [1 ,2 ]
Wang, Jianjun [1 ,2 ]
Shu, Zhan [1 ,2 ]
Tang, Aidong [3 ]
Yang, Huaming [1 ,2 ]
机构：
[1] Cent S Univ, Sch Minerals Proc & Bioengn, Ctr Mineral Mat, Changsha 410083, Peoples R China
[2] Cent S Univ, Key Lab Mineral Mat & Applicat Hunan Prov, Changsha 410083, Peoples R China
[3] Cent S Univ, Sch Chem & Chem Engn, Changsha 410083, Peoples R China
来源：
RSC ADVANCES | 2016年 / 6卷 / 48期
基金：
中国国家自然科学基金;
关键词：
HEAVY-METALS; DYE; ADSORPTION; NANOPARTICLES; PHOTODEGRADATION; NANOCOMPOSITE; OXIDATION; COMPOSITE; HYDROGEN; ACID;
D O I：
10.1039/c6ra04350j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Y2O3 functioned palygorskite (Pal) composite as a novel adsorbent has been successfully synthesized and characterized, which shows stable and rapid decolorization performance for methyl blue (MB). HRTEM images showed that Y2O3 nanoparticles with size about 2-5 nm evenly dispersed on palygorskite, and the increase of the binding energy of Y2O3 (Y3d(5/2)) confirmed that several bonds such as Y-OH and Y-O-Si were existed in Y2O3/Pal adsorbent. Y2O3 modification greatly increased the number of negatively charged groups as Y2O3/Pal showed lower negative zeta potential than that of Pal. Therefore, the electrostatic interaction between Y2O3/Pal and MB is impossible to be the adsorption mechanism. What's more, it is found that the adsorption isotherm obeys the Langmuir model, with the maximum adsorption capacity greatly enhanced to 1579.06 mg g(-1), exhibiting potential applications in wastewater treatment.
引用
收藏
页码：41765 / 41771
页数：7
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