Manganese-N-heterocyclic carbene (NHC) complexes - An overview

被引：10

作者：

Vanden Broeck, Sofie M. P. ^{[1
]}

Cazin, Catherine S. J. ^{[1
]}

机构：

[1] Ctr Sustainable Chem, Dept Chem, Krijgslaan 281-S3, B-9000 Ghent, Belgium

来源：

POLYHEDRON | 2021年 / 205卷

关键词：

N-heterocyclic carbenes; Manganese; Organometallic complexes; Catalysis; TRANSITION-METAL-COMPLEXES; ELECTROCATALYTIC REDUCTION; DIVALENT MANGANESE; OXIDATION; LIGAND; BEARING; REACTIVITY; KETONES; ACCESS; COBALT;

D O I：

10.1016/j.poly.2021.115204

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

N-heterocyclic carbenes (NHCs) have been extensively used as ligands in organometallic complexes of the Transition Metals. This review focuses on manganese complexes bearing these NHC ligands. An overview is given of all complexes of manganese in various oxidation states, as well as their use in catalytic reactions, principally in CO2 reduction, hydrosilylation and alkylation. (C) 2021 Published by Elsevier Ltd.

引用

页数：17

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