Formic acid catalyzed one-pot synthesis of α-aminophosphonates: an efficient, inexpensive and environmental friendly organocatalyst

被引：1

作者：

Mehraban, Jamshid Azarnia ^{[1
]}

Jalali, Mahsa Sadat ^{[1
]}

Heydari, Akbar ^{[1
]}

机构：

[1] Tarbiat Modares Univ, Chem Dept, Tehran, Iran

来源：

CHEMICAL PAPERS | 2018年 / 72卷 / 09期

关键词：

alpha-Aminophosphonates; Formic acid; Organocatalyst; Kabachnik-Fields reaction; KABACHNIK-FIELDS REACTION; AMINO PHOSPHONATES; SOLVENT-FREE; BIOLOGICAL-ACTIVITY; DIASTEREOSELECTIVE SYNTHESIS; MULTICOMPONENT SYNTHESIS; 3-COMPONENT SYNTHESIS; REUSABLE CATALYST; HYDROGEN STORAGE; FACILE SYNTHESIS;

D O I：

10.1007/s11696-018-0434-6

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aqueous formic acid is used for the synthesis of alpha-aminophosphonates through Kabachnik-Fields reaction applying aromatic amine, phosphite, and carbonyl compounds. Using formic acid as an efficient and low-cost organocatalyst provides environmental friendly, high yields, low reaction time and mild reaction condition. The isolated products were analyzed by IR, NMR, and mass techniques. [GRAPHICS] .

引用

页码：2215 / 2223

页数：9

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