Preparation and characterization of lamellar-like Mg(OH)2 nanostructures via natural oxidation of Mg metal in formamide/water mixture

被引:53
作者
Zou, Guanglong [1 ]
Liu, Run [1 ]
Chen, Weixiang [1 ]
Xu, Zhude [1 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
基金
高等学校博士学科点专项科研基金;
关键词
nanostructures; inorganic compounds; chemical synthesis; electron microscopy;
D O I
10.1016/j.materresbull.2006.09.008
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Facile, scale-up, and controllable fabrication of lamellar-like Mg(OH)(2) on a magnesium substrate through natural oxidation of Mg metal in formamide/water mixtures has been demonstrated. The one-step, wet-chemical approach has displayed well-controlled growth of densely packed magnesium hydroxide with large-area homogeneity and uniform morphology. The chemical-liquid-deposition process, an analogue to the widely used chemical-vapor-deposition technique, has been well developed for production of specific morphological Mg(OH)(2) through continuous supply, transport, and thermal decomposition of magnesium complexes in a liquid phase. The formation mechanism of lamellar-like Mg(OH)(2) was also discussed based on experimental phenomena. (C). 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1153 / 1158
页数:6
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