An assessment of activated carbon cloth microporosity change due to chemical activation

被引:10
作者
Badalyan, A. [1 ]
Bromball, R. [1 ]
Pendleton, P. [1 ]
Skinner, W. [2 ]
机构
[1] Univ S Australia, Sansom Inst, Ctr Mol & Mat Sci, Adelaide, SA 5000, Australia
[2] Univ S Australia, Ian Wark Res Inst, Mawson Lakes, SA 5000, Australia
关键词
GAS-ADSORPTION MEASUREMENTS; SURFACE-CHEMISTRY; WATER; ALPHA(S)-ANALYSES; UNCERTAINTIES; DISINFECTION; MECHANISM; KINETICS; AMMONIA; FIBERS;
D O I
10.1016/j.carbon.2009.11.019
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Controlled modification of micropore volumes of samples from the FM1-series of activated carbon cloth can be achieved via selective oxidation: strong caustic treatment leads to an increase in volume, while peroxydisulfate treatment leads to a decrease in volume. Pore volume increases are determined to be due to inorganic content leaching, determined via XPS analyses, developing small primary micropores for the least activated carbon cloth (FM1/250) and a widening of the pore width for the most activated carbon cloth (FM1/700). All cloths exhibited Type I nitrogen adsorption isotherms both prior to and post oxidative treatment. (C) 2009 Elsevier Ltd. All rights reserved.
引用
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页码:1004 / 1011
页数:8
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