Self-catalyzed growth of GaSb nanowires at low reaction temperatures

被引:19
作者
Schulz, Stephan [1 ,2 ]
Schwartz, Marcel [1 ,2 ]
Kuczkowski, Andreas [1 ,2 ]
Assenmacher, Wilfried [3 ]
机构
[1] Univ Duisburg Essen, Dept Chem, D-45117 Essen, Germany
[2] Univ Duisburg Essen, CeNIDE, D-45117 Essen, Germany
[3] Univ Bonn, Dept Chem, D-53117 Bonn, Germany
关键词
Nanostructures; Metalorganic chemical vapor deposition; Antimonides; Semiconducting gallium compounds; LIQUID-SOLID MECHANISM; GAAS; SEMICONDUCTORS; DECOMPOSITION; ANTIMONIDE; DISTIBANES; GALLIUM; PHYSICS; ARRAYS;
D O I
10.1016/j.jcrysgro.2010.01.026
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Thermal decomposition of Lewis acid-base adducts [t-Bu3Ga-Sbi-Pr-3] (1) and [t-Bu3Ga](2)[Sb2Et4] (2) in closed glass ampoules at temperatures between 250 and 350 degrees C yielded crystalline GaSb nanowires. Isolated GaSb nanowires were formed preferably at low decomposition temperatures, whereas dendritic-like growth was observed at higher decomposition temperatures. In addition, self-catalyzed growth of GaSb nanowires using 90 nm-sized Ga droplets, which were pre-deposited on Si(1 0 0) substrates, was achieved with the distibine Sb2Et4 at 250 degrees C (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1475 / 1480
页数:6
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