A photochromic system based on photochemical or thermal chelate exchange on Ru(phen)2L2+ (L = diimine or dinitrile ligand)

被引：26

作者：

Baranoff, E ^{[1
]}

Collin, JP ^{[1
]}

Furusho, Y ^{[1
]}

Laemmel, AC ^{[1
]}

Sauvage, JP ^{[1
]}

机构：

[1] Univ Strasbourg, Fac Chim, Lab Chim Organominerale, CNRS,UMR 7513, F-67070 Strasbourg, France

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 19期

关键词：

D O I：

10.1039/b004982o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of a bidentate chelate containing two convergent nitrile groups, Ru(phen)(2)L2+ (L = sterically hindering aromatic diimine ligand; phen = 1,10-phenanthroline) undergoes a photochemical reaction leading to quantitative replacement of the diimine by the bis-nitrile ligand; the reverse reaction takes place upon heating, also quantitatively.

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收藏

页码：1935 / 1936

页数：2

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