A photochromic system based on photochemical or thermal chelate exchange on Ru(phen)2L2+ (L = diimine or dinitrile ligand)

被引：26
作者：
Baranoff, E [1 ]
Collin, JP [1 ]
Furusho, Y [1 ]
Laemmel, AC [1 ]
Sauvage, JP [1 ]
机构：
[1] Univ Strasbourg, Fac Chim, Lab Chim Organominerale, CNRS,UMR 7513, F-67070 Strasbourg, France
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 19期
关键词：
D O I：
10.1039/b004982o
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the presence of a bidentate chelate containing two convergent nitrile groups, Ru(phen)(2)L2+ (L = sterically hindering aromatic diimine ligand; phen = 1,10-phenanthroline) undergoes a photochemical reaction leading to quantitative replacement of the diimine by the bis-nitrile ligand; the reverse reaction takes place upon heating, also quantitatively.
引用
收藏
页码：1935 / 1936
页数：2
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