High performance of thick amorphous columnar monolithic film silicon anodes in ionic liquid electrolytes at elevated temperature

被引：20

作者：

Markevich, E. ^{[1
]}

Salitra, G. ^{[1
]}

Rosenman, A. ^{[1
]}

Talyosef, Y. ^{[1
]}

Aurbach, D. ^{[1
]}

Garsuch, A. ^{[1
]}

机构：

[1] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel

来源：

RSC ADVANCES | 2014年 / 4卷 / 89期

基金：

以色列科学基金会;

关键词：

BATTERIES; SI;

D O I：

10.1039/c4ra09413a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cycling performance of thick (about 7 mm) amorphous columnar monolithic film silicon anodes was studied in ionic liquid based electrolyte solutions. Cycling results obtained for these Si anodes in 1-methyl-1-propylpyrrolidinium bis(fluorosulfonyl)imide-based electrolyte solutions are superior to those demonstrated in LiPF6/fluoroethylene carbonate/dimethyl carbonate electrolyte solution under identical conditions.

引用

收藏

页码：48572 / 48575

页数：4

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共 12 条

[1] Amorphous silicon thin films as a high capacity anodes for Li-ion batteries in ionic liquid electrolytes [J].

Baranchugov, V. ;

Markevich, E. ;

Pollak, E. ;

Salitra, G. ;

Aurbach, D. .

ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (04) :796-800

[2] Quaternary Ammonium Ionic Liquid Electrolyte for a Silicon Nanowire-Based Lithium Ion Battery [J].

Chakrapani, Vidhya ;

Rusli, Florencia ;

Filler, Micheal A. ;

Kohl, Paul A. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (44) :22048-22053

[3] Electrochemical performance of nanoporous Si as anode for lithium ion batteries in alkyl carbonate and ionic liquid-based electrolytes [J].

Ivanov, S. ;

Vlaic, C. A. ;

Du, S. ;

Wang, D. ;

Schaaf, P. ;

Bund, A. .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 2014, 44 (01) :159-168

[4] Pair Distribution Function Analysis and Solid State NMR Studies of Silicon Electrodes for Lithium Ion Batteries: Understanding the (De)lithiation Mechanisms [J].

Key, Baris ;

Morcrette, Mathieu ;

Tarascon, Jean-Marie ;

Grey, Clare P. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (03) :503-512

[5] Energy applications of ionic liquids [J].

MacFarlane, Douglas R. ;

Tachikawa, Naoki ;

Forsyth, Maria ;

Pringle, Jennifer M. ;

Howlett, Patrick C. ;

Elliott, Gloria D. ;

Davis, James H., Jr. ;

Watanabe, Masayoshi ;

Simon, Patrice ;

Angell, C. Austen .

ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (01) :232-250

[6] Amorphous Columnar Silicon Anodes for Advanced High Voltage Lithium Ion Full Cells: Dominant Factors Governing Cycling Performance [J].

Markevich, E. ;

Fridman, K. ;

Sharabi, R. ;

Elazari, R. ;

Salitra, G. ;

Gottlieb, H. E. ;

Gershinsky, G. ;

Garsuch, A. ;

Semrau, G. ;

Schmidt, M. A. ;

Aurbach, D. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2013, 160 (10) :A1824-A1833

[7] Ionic Liquid Electrolytes for Lithium-Sulfur Batteries [J].

Park, Jun-Woo ;

Ueno, Kazuhide ;

Tachikawa, Naoki ;

Dokko, Kaoru ;

Watanabe, Masayoshi .

JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (40) :20531-20541

[8] Thermal stability of lithium-ion battery electrolytes [J].

Ravdel, B ;

Abraham, KM ;

Gitzendanner, R ;

DiCarlo, J ;

Lucht, B ;

Campion, C .

JOURNAL OF POWER SOURCES, 2003, 119 :805-810

[9] Application of bis(fluorosulfonyl)imide-based ionic liquid electrolyte to silicon-nickel-carbon composite anode for lithium-ion batteries [J].

Sugimoto, Toshinori ;

Atsumi, Yosuke ;

Kono, Michiyuki ;

Kikuta, Manabu ;

Ishiko, Eriko ;

Yamagata, Masaki ;

Ishikawa, Masashi .

JOURNAL OF POWER SOURCES, 2010, 195 (18) :6153-6156

[10] Applicability of ionic liquid electrolytes to LaSi2/Si composite thick-film anodes in Li-ion battery [J].

Usui, Hiroyuki ;

Shimizu, Masahiro ;

Sakaguchi, Hiroki .

JOURNAL OF POWER SOURCES, 2013, 235 :29-35