Europium doped zirconia luminescence

被引:108
作者
Smits, Krisjanis [1 ]
Grigorjeva, Larisa [1 ]
Millers, Donats [1 ]
Sarakovskis, Anatolijs [1 ]
Opalinska, Agnieszka [2 ]
Fidelus, Janusz D. [2 ]
Lojkowski, Witold [2 ]
机构
[1] Univ Latvia, Inst Solid State Phys, Riga, Latvia
[2] Res Inst High Pressure Phys, Warsaw, Poland
关键词
Zirconia; Luminescence; Eu3+; Crystalline structure; NANOCRYSTALS; PHOTOLUMINESCENCE; IONS;
D O I
10.1016/j.optmat.2010.03.002
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The luminescence properties and crystalline structure of ZrO2:Eu nanocrystals doped with different concentrations of Eu were studied. Luminescence from the Eu2+ state was not observed even if the electrons and holes were created up to similar to 10(19) cm(-3); thus it was suggested the Eu3+ was not an efficient trap for electrons possibly due to Eu3+ negative charge relative to the crystalline lattice. The mutual interaction between Eu3+ ions was not strong up to 5 at.% concentration. The stabilization of ZrO2 tetragonal as well as cubic structure by Eu3+ is possible. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:827 / 831
页数:5
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