Coordination ability of N,N'-disubstituted 9,10-phenanthrenediimines

被引:8
作者
Abakumov, G. A. [1 ,2 ]
Druzhkov, N. O. [1 ]
Kocherova, T. N. [1 ]
Kozhanov, K. A. [1 ]
Murugova, A. V. [2 ]
Egorova, E. N. [1 ]
机构
[1] Razyvaev Inst Organometall Chem, Ul Tropinina 49, Nizhnii Novgorod 603950, Russia
[2] NI Lobachevskii State Univ, Pr Gagarina 23, Nizhnii Novgorod 603950, Russia
基金
俄罗斯基础研究基金会;
关键词
METAL; COMPLEXES;
D O I
10.1134/S0012500816040017
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The ability of N,N'-disubstituted 9,10-phenanthrenediimines in neutral, monoand direduced states to act as bidentate ligands in main-group-metal and transition-metal complexes has been demonstrated for the first time. The formation of metal complexes with the radical anion form of phenanthrenediimines stabilized through the formation of contact pairs (for Li) or chelate complexes (for Rh) has been detected.
引用
收藏
页码:109 / 112
页数:4
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