Rhodium-Catalyzed Synthesis of Dialkyl(Heteroaryl)Phosphine Sulfides by Phosphinylation of Heteroaryl Sulfides

被引：9
作者：
Arisawa, Mieko [1 ]
Tazawa, Takeru [1 ]
Ichinose, Wataru [1 ]
Kobayashi, Haruki [1 ]
Yamaguchi, Masahiko [1 ]
机构：
[1] Tohoku Univ, Grad Sch Pharmaceut Sci, Dept Organ Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2018年 / 360卷 / 18期
关键词：
dialkyl(heteroaryl)phosphine sulfides; tetraalkyldiphosphine disulfides; phosphinylation; desulfurization; Rh catalysis; PHOSPHONIUM IONIC LIQUIDS; METAL-FREE; DIARYLPHOSPHINE OXIDES; DIRECT PHOSPHORYLATION; ROOM-TEMPERATURE; ARYL CHLORIDES; DIPHENYLPHOSPHINE; HETEROCYCLES; DERIVATIVES; COMPLEXES;
D O I：
10.1002/adsc.201800630
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Dialkyl(heteroaryl) phosphine sulfides were synthesized by the rhodium-catalyzed exchange reaction of heteroaryl aryl sulfides and tetraalkyldiphosphine disulfides. The reaction has a broad applicability, giving diverse dialkyl(heteroaryl) phosphine sulfides containing five-and six-membered heteroaryl groups. Various dialkyl(heteroaryl) phosphines were obtained by desulfurization.
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页码：3488 / 3491
页数：4
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