An Atomic-Scale View of CO and H2 Oxidation on a Pt/Fe3O4 Model Catalyst

被引：79

作者：

Bliem, Roland ^{[1
]}

van der Hoeven, Jessi ^{[2
]}

Zavodny, Adam ^{[3
,4
]}

Gamba, Oscar ^{[1
]}

Pavelec, Jiri ^{[1
]}

de Jongh, Petra E. ^{[2
]}

Schmid, Michael ^{[1
]}

Diebold, Ulrike ^{[1
]}

Parkinson, Gareth S. ^{[1
]}

机构：

[1] TU Wien, Inst Appl Phys, A-1050 Vienna, Austria

[2] Univ Utrecht, Debye Inst Nanomat, NL-3508 TA Utrecht, Netherlands

[3] Brno Univ Technol, Inst Engn Phys, Brno 61669, Czech Republic

[4] Brno Univ Technol, CEITEC BUT, Brno 61669, Czech Republic

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 47期

基金：

奥地利科学基金会; 欧洲研究理事会;

关键词：

Mars-van Krevelen mechanism; metal-support interactions; oxide surfaces; scanning probe microscopy; supported catalysts; GOLD CATALYSTS; SUPPORT; REDUCTION; INTERFACE; OXYGEN; WATER; SIZE; SURFACE; PHASE; TIO2;

D O I：

10.1002/anie.201507368

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-support interactions are frequently invoked to explain the enhanced catalytic activity of metal nanoparticles dispersed over reducible metal oxide supports, yet the atomic-scale mechanisms are rarely known. In this report, scanning tunneling microscopy was used to study a Pt1-6/Fe3O4 model catalyst exposed to CO, H-2, O-2, and mixtures thereof at 550 K. CO extracts lattice oxygen atoms at the cluster perimeter to form CO2, creating large holes in the metal oxide surface. H-2 and O-2 dissociate on the metal clusters and spill over onto the support. The former creates surface hydroxy groups, which react with the support, ultimately leading to the desorption of water, while oxygen atoms react with Fe from the bulk to create new Fe3O4(001) islands. The presence of the Pt is crucial because it catalyzes reactions that already occur on the bare iron oxide surface, but only at higher temperatures.

引用

页码：13999 / 14002

页数：4

共 37 条

[11] Reducibility of supported gold (III) precursors: influence of the metal oxide support and consequences for CO oxidation activity [J].