Synthesis of enantiopure 3-hydroxymethylchromanes via intramolecular nitrone cycloaddition

被引：34
|
作者：
Broggini, G
Folcio, F
Sardone, N
Sonzogni, M
Zecchi, G
机构：
[1] UNIV MILAN,DIPARTIMENTO CHIM ORGAN & IND,I-20133 MILAN,ITALY
[2] UNIV PAVIA,CTR GRANDI STRUMENTI,I-27100 PAVIA,ITALY
来源：
TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 03期
关键词：
D O I：
10.1016/0957-4166(96)00076-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Enantiopure (R) and (S) 3-hydroxymethylchromanes were prepared by the intramolecular nitrone cycloaddition strategy, starting from allyl-type ethers of 2-hydroxybenzaldehydes and using (R)-N-(alpha-phenylethyl)hydroxylamine as chiral auxiliary.
引用
收藏
页码：797 / 806
页数：10
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