Novel interpenetrating and non-interpenetrating structures based on semi-rigid 4,4′-biphenyl-based ligand

被引：16

作者：

Chang, Yushan ^{[1
]}

Xu, Hong ^{[1
]}

Xie, Shaopei ^{[1
]}

Li, Jinpeng ^{[1
]}

Xue, Xuling ^{[1
]}

Hou, Hongwei ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Henan, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 08期

基金：

中国国家自然科学基金;

关键词：

Biphenyl; Crystal structure; DRS UV/Vis; Second-order NLO effects; NONLINEAR-OPTICAL PROPERTIES; COORDINATION POLYMERS; CRYSTAL; FRAMEWORKS; ZN;

D O I：

10.1016/j.inoche.2010.05.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of semi-rigid bidentate ligand 4,4'-bis(benzimidazol-1-ylmethyl)biphenyl (bbmb) with NiCl2 and CuCl2 and Cd(OAc)(2) afford novel complexes {[M(bbmb)(2)(Cl)(OH)](H2O)(2)}(n) (M = Ni(1), Cu(2)) and [Cd-2(OAc)(4)(bbmb)(3)](2)(CH3OH)(3)(H2O)(2) (3). Both complexes 1 and 2 feature parallel 2-fold interpenetrating (4,4)-windmill-like layer morphology. Complex 3 presents unique discrete quad-nuclear motif comprised by two couples of alternating single and double twisting chains. The three complexes exhibit active second-order NLO effects. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：959 / 963

页数：5

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