Exploration of mixed valence chemistry:: Inventing new analogues of the Creutz-Taube ion

被引：312

作者：

Kaim, W ^{[1
]}

Klein, A ^{[1
]}

Glöckle, M ^{[1
]}

机构：

[1] Univ Stuttgart, Inst Anorgan Chem, D-70550 Stuttgart, Germany

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2000年 / 33卷 / 11期

关键词：

D O I：

10.1021/ar960067k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Starting from the Creutz-Taube ion as the prototype of a molecule-bridged mixed-valent complex, a number of related systems are presented in which the metal, the co-ligands, the molecular bridge, the d electron configuration, the medium, the charge, the coordination mode, or the nuclearity have been modified. The new mixed-valent configurations, as obtained through various chemical approaches, display different stabilities and spectroscopic characteristics in relation to the Creutz-Taube ion; the analysis of these results serves to provide a better understanding of fundamental aspects of molecule-mediated metal-metal interaction.

引用

页码：755 / 763

页数：9

共 75 条

[31] BINUCLEAR COMPLEXES OF RUTHENIUM AND OSMIUM BRIDGED BY 2,2'-BIBENZIMIDAZOLATE - PREPARATION, ELECTROCHEMISTRY, AND FORMATION OF MIXED-VALENCE COMPLEXES [J].

HAGA, M ;

MATSUMURAINOUE, T ;

YAMABE, S .

INORGANIC CHEMISTRY, 1987, 26 (25) :4148-4154

[32] Spectroelectrochemical characterization of the two-step redox system {(μ-pz)[Os(CN)5]2}n- (n = 4, 5, 6; pz = pyrazine).: Similarities and differences in relation to the Creutz-Taube system [J].

Hornung, FM ;

Baumann, F ;

Kaim, W ;

Olabe, JA ;

Slep, LD ;

Fiedler, J .

INORGANIC CHEMISTRY, 1998, 37 (02) :311-316

[33] RUTHENIUM(II)-BIPYRIMIDINE COMPLEXES - SPECTROSCOPIC AND ELECTROCHEMICAL PROPERTIES OF A NOVEL SERIES OF COMPOUNDS [J].

HUNZIKER, M ;

LUDI, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (22) :7370-7371

[34] DISTANCE DEPENDENCE OF ELECTRON-TRANSFER RATES [J].

HUSH, NS .

COORDINATION CHEMISTRY REVIEWS, 1985, 64 (MAY) :135-157

[35] Electron transfer on the infrared vibrational time scale in-the mixed valence state of 1,4-pyrazine- and 4,4′-bipyridine-bridged ruthenium cluster complexes [J].

Ito, T ;

Hamaguchi, T ;

Nagino, H ;

Yamaguchi, T ;

Kido, H ;

Zavarine, IS ;

Richmond, T ;

Washington, J ;

Kubiak, CP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (19) :4625-4632

[36] SPECTROSCOPY OF MIXED VALENT STATES IN DINUCLEAR IONS AND METALLOPROTEINS [J].

KAIM, W ;

BRUNS, W ;

POPPE, J ;

KASACK, V .

JOURNAL OF MOLECULAR STRUCTURE, 1993, 292 :221-228

[37] STABILITY RULES FOR D5/D6 MIXED-VALENT DIMERS - EFFECTS FROM THE DONOR-ACCEPTOR CAPABILITY OF THE METAL (RU VS OS) AND FROM THE OCCUPANCY OF THE MEDIATING LIGAND ORBITAL (LUMO VS HOMO) [J].

KAIM, W ;

KASACK, V .

INORGANIC CHEMISTRY, 1990, 29 (23) :4696-4699

[38]

KAIM W, 1995, Z NATURFORSCH B, V50, P123

[39] METAL-METAL INTERACTION IN LIGAND-BRIDGED DIMOLYBDENUM(0,0) AND DIMOLYBDENUM(I,0) COMPLEXES WITH VERY SMALL FRONTIER ORBITAL GAPS - ELECTROCHEMISTRY AND SPECTROSCOPIC PROPERTIES OF 3 NEIGHBORING OXIDATION-STATES [J].

KAIM, W ;

BRUNS, W ;

KOHLMANN, S ;

KREJCIK, M .

INORGANICA CHIMICA ACTA, 1995, 229 (1-2) :143-151

[40] Ligand-mediated coupling of organometallic reaction centers [J].

Kaim, W ;

Reinhardt, R ;

Fiedler, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (22) :2493-2495

← 1 2 3 4 5 6 7 8 →