Exploration of mixed valence chemistry:: Inventing new analogues of the Creutz-Taube ion

被引：312

作者：

Kaim, W ^{[1
]}

Klein, A ^{[1
]}

Glöckle, M ^{[1
]}

机构：

[1] Univ Stuttgart, Inst Anorgan Chem, D-70550 Stuttgart, Germany

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2000年 / 33卷 / 11期

关键词：

D O I：

10.1021/ar960067k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Starting from the Creutz-Taube ion as the prototype of a molecule-bridged mixed-valent complex, a number of related systems are presented in which the metal, the co-ligands, the molecular bridge, the d electron configuration, the medium, the charge, the coordination mode, or the nuclearity have been modified. The new mixed-valent configurations, as obtained through various chemical approaches, display different stabilities and spectroscopic characteristics in relation to the Creutz-Taube ion; the analysis of these results serves to provide a better understanding of fundamental aspects of molecule-mediated metal-metal interaction.

引用

页码：755 / 763

页数：9

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