A Novel Visible Light-Driven p-Type BiFeO3/n-Type SnS2 Heterojunction Photocatalyst for Efficient Charge Separation and Enhanced Photocatalytic Activity

被引:17
作者
Arunkumar, M. [1 ]
Veerakumar, S. [2 ]
Mohanavel, V. [3 ]
Vairamuthu, J. [4 ]
Vijayan, V. [5 ]
Senthilkumar, N. [6 ]
机构
[1] Sri Shakthi Inst Engn & Technol, Dept Agr Engn, Coimbatore 641062, Tamil Nadu, India
[2] Sri Ramakrishna Inst Technol, Dept Mech Engn, Coimbatore 641010, Tamil Nadu, India
[3] Bharath Inst Higher Educ & Res, Ctr Mat Engn & Regenerat Med, Chennai 600073, Tamil Nadu, India
[4] Sethu Inst Technol, Dept Mech Engn, Pulloor 626115, Tamil Nadu, India
[5] K Ramakrishnan Coll Technol, Dept Mech Engn, Trichy 621112, Tamil Nadu, India
[6] M Kumarasamy Coll Engn, Dept Elect & Commun Engn, Karur 639113, Tamil Nadu, India
关键词
p-type BiFeO3; n-type SnS2 heterostructure; Two-step synthesis approach; Structural; Optical; Visible light photocatalytic activity; N HETEROJUNCTION; BIFEO3; NANOCOMPOSITE; DEGRADATION; NANOFIBERS; TIO2; CAPABILITY; ZNO;
D O I
10.1007/s10876-021-02114-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This present investigation focused on novel p-type bismuth ferrite (BiFeO3)/n-type tin sulfide (SnS2) heterostructure photocatalyst has been favorably attained via a facile two-step process followed by co-precipitation approach for enhances the photocatalytic activity through the degradation of Methylene Blue (MB) and Rhodamine B (RhB) organic dyes under visible-light illumination. Structural, optical, and photocatalytic behavior of the prepared BiFeO3 and BiFeO3/SnS2 photocatalysts are carefully explored. The photocatalytic efficiency of BiFeO3/SnS2 nanocatalyst was calculated to be 83%, 78% for MB and RhB, respectively, within 120 min illumination whereas the pure BiFeO3 nanoparticle was 58% and 56% for MB and RhB. This prominent enhancement of visible light photocatalytic activity can be ascribed to the separation as well as the transfer of photogenerated charge carriers, successful exploitation of visible light absorption and donates the enlarged number of photocatalytic active sites by the formation of BiFeO3/SnS2 p-n heterojunction.
引用
收藏
页码:1431 / 1439
页数:9
相关论文
共 30 条
[1]   Facile synthesis of solar light active spinel nickel manganite (NiMn2O4) by co-precipitation route for photocatalytic application [J].
Abel, M. John ;
Pramothkumar, A. ;
Archana, V ;
Senthilkumar, N. ;
Jothivenkatachalam, K. ;
Prince, J. Joseph .
RESEARCH ON CHEMICAL INTERMEDIATES, 2020, 46 (07) :3509-3525
[2]   Flake-like CuMn2O4 nanoparticles synthesized via co-precipitation method for photocatalytic activity [J].
Abel, M. John ;
Pramothkumar, A. ;
Senthilkumar, N. ;
Jothivenkatachalam, K. ;
Inbaraj, P. Fermi Hilbert ;
Prince, J. Joseph .
PHYSICA B-CONDENSED MATTER, 2019, 572 :117-124
[3]   Highly efficient Y and V co-doped ZnO photocatalyst with enhanced dye sensitized visible light photocatalytic activity [J].
Alam, Umair ;
Khan, Azam ;
Raza, Waseem ;
Khan, Abuzar ;
Bahnemann, Detlef ;
Muneer, M. .
CATALYSIS TODAY, 2017, 284 :169-178
[4]   Green Synthesis and Electrical Properties of p-CuO/n-ZnO Heterojunction Diodes [J].
Annathurai, Sridevi ;
Chidambaram, Siva ;
Baskaran, Balraj ;
Venkatesan, G. K. D. Prasanna .
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2019, 29 (02) :535-540
[5]   A new SnS2-BiFeO3/reduced graphene oxide photocatalyst with superior photocatalytic capability under visible light irradiation [J].
Bagherzadeh, Mojtaba ;
Kaveh, Reyhaneh .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2018, 359 :11-22
[6]   A visible-light-active BiFeO3/ZnS nanocomposite for photocatalytic conversion of greenhouse gases [J].
Bagvand, Nasim ;
Sharifnia, Shahram ;
Karamian, Elham .
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2018, 35 (08) :1735-1740
[7]   Enhanced Photocatalytic Activity and Biosensing of Gadolinium Substituted BiFeO3 Nanoparticles [J].
Basavarajappa, Patil S. ;
Seethya, Bhojya Naik H. ;
Ganganagappa, Nagaraju ;
Eshwaraswamy, Kumaraswamy B. ;
Kakarla, Raghava Reddy .
CHEMISTRYSELECT, 2018, 3 (31) :9025-9033
[8]   Wet chemical synthesis and characterization of SnS2 nanoparticles [J].
Chaki, Sunil H. ;
Deshpande, M. P. ;
Trivedi, Devangini P. ;
Tailor, Jiten P. ;
Chaudhary, Mahesh D. ;
Mahato, Kanchan .
APPLIED NANOSCIENCE, 2013, 3 (03) :189-195
[9]   Facile Synthesis and Enhanced Visible-Light Photocatalytic Activity of Novel p-Ag3PO4/n-BiFeO3 Heterojunction Composites for Dye Degradation [J].
Di, Lijing ;
Yang, Hua ;
Xian, Tao ;
Chen, Xiujuan .
NANOSCALE RESEARCH LETTERS, 2018, 13
[10]   Fabrication of visible light active BiFeO3/CuS/SiO2 Z-scheme photocatalyst for efficient dye degradation [J].
Dutta, Vishal ;
Sharma, Sheetal ;
Raizada, Pankaj ;
Hosseini-Bandegharaei, Ahmad ;
Kaushal, Jyotsana ;
Singh, Pardeep .
MATERIALS LETTERS, 2020, 270