Direct halogenation of organic compounds with halides using oxone in water - A green protocol

被引：26

作者：

Firouzabadi, H. ^{[1
]}

Iranpoor, N. ^{[1
]}

Kazemi, S. ^{[1
]}

机构：

[1] Shiraz Univ, Dept Chem, Coll Sci, Shiraz 71454, Iran

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 2009年 / 87卷 / 12期

关键词：

iodination; bromination; oxone; water; DODECYL-SULFATE SDS; AROMATIC-COMPOUNDS; HYDROGEN-PEROXIDE; MICELLAR-SOLUTION; POTASSIUM-IODIDE; MICHAEL ADDITION; TETRABUTYLAMMONIUM PEROXYDISULFATE; REGIOSELECTIVE OXYIODINATION; COUPLING REACTIONS; IODINATION METHOD;

D O I：

10.1139/V09-125

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct bromination and iodination of various aromatic compounds with NaBr and Nal using oxone (2KHSO(5)center dot KHSO(4)center dot K(2)SO(4)) in water was accomplished successfully in high-to-excel lent yields. The main benefit of this protocol is the performance of the reactions in water in the presence of a harmless oxidant without the use of any organic co-solvents. Using NaBr and Nal as the safe sources of halogens is another advantage of the protocol. This method is easily applicable to the large-scale operations. We have also applied this method successfully for the iodocyclization of an unsaturated alcohol and an unsaturated carboxylic acid.

引用

页码：1675 / 1681

页数：7

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