Pincer-Supported Carbonyl Complexes of Cobalt(I)

被引：22
|
作者：
Guard, Louise M. [1 ]
Hebden, Travis J. [1 ]
Linn, Donald E., Jr. [2 ]
Heinekey, D. Michael [1 ]
机构：
[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA
[2] Indiana Univ Purdue Univ, Dept Chem, 2101 Coliseum Blvd,East Sci Bldg 496, Ft Wayne, IN 46805 USA
来源：
ORGANOMETALLICS | 2017年 / 36卷 / 16期
关键词：
M(CO)(4) M=NI; TRANSFER DEHYDROGENATION; ALKANE DEHYDROGENATION; OXIDATIVE ADDITION; IRIDIUM CATALYSTS; RHODIUM; REACTIVITY; BOND; OS; RU;
D O I：
10.1021/acs.organomet.7b00434
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A pair of POCOP-supported mono- and dicarbonyl complexes of Co have been prepared and crystallographically characterized. The reactivity of ((POCOP)-P-tBu)Co(CO) with H-2, acids, and carbon monoxide has been compared to that of the previously reported Rh and Ir counterparts. Co is found to share reactivity traits with both Rh and Ir.
引用
收藏
页码：3104 / 3109
页数：6
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