A bench-stable N-trifluoroacetyl nitrene equivalent for a simple synthesis of 2-trifluoromethyl oxazoles

被引：13
作者：
Kobayashi, Yusuke [1 ]
Masakado, Sota [2 ]
Murai, Takuya [1 ]
Hamada, Shohei [1 ]
Furuta, Takumi [1 ]
Takemoto, Yoshiji [2 ]
机构：
[1] Kyoto Pharmaceut Univ, Dept Pharmaceut Chem, Yamashina Ku, Kyoto 6078414, Japan
[2] Kyoto Univ, Grad Sch Pharmaceut Sci, Sakyo Ku, Kyoto 6068501, Japan
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2021年 / 19卷 / 30期
关键词：
C-H-AMINATION; ALKENES; AZIRIDINATION; BONDS; PHOTOCHEMISTRY; REACTIVITY; INHIBITORS; MECHANISM; OXIDATION; REAGENTS;
D O I：
10.1039/d1ob00947h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
ortho-Nitro-substituted N-trifluoroacetyl imino-lambda(3)-iodane is a bench-stable trifluoroacetyl nitrene precursor, in which intra- and intermolecular halogen bonding (XB) plays an important role. Potential synthetic applications of this novel precursor were explored.
引用
收藏
页码：6628 / 6632
页数：5
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