Facile C-H bond activation on a transient gallium imide

被引：5

作者：

Kassymbek, Aishabibi ^{[1
]}

Spasyuk, Denis ^{[2
]}

Dmitrienko, Anton ^{[1
]}

Pilkington, Melanie ^{[1
]}

Nikonov, Georgii I. ^{[1
]}

机构：

[1] Brock Univ, Dept Chem, 1812 Sir Isaac Brock Way, St Catharines, ON L2S 3A1, Canada

[2] Canadian Light Source Inc, 44 Innovat Blvd, Saskatoon, SK S7N 2V3, Canada

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 49期

基金：

加拿大自然科学与工程研究理事会;

关键词：

MONOMERIC IMIDES; ALUMINUM; REACTIVITY; AL; ISOMERIZATION; IMINOALANE; CARBENE; LAL; AR'; GA;

D O I：

10.1039/d2cc01857h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of NacNacGa with azide N3SiMe3 results in the generation of a transient imide NacNacGa(=NSiMe3) that can cleave unactivated sp(3) C-H and sp(2) C-H bonds of different substrates, affording gallium amides. Pyridine, cyclohexanone, ethyl acetate, DMSO, and triethylphosphine oxide were activated in this process producing corresponding gallium amides. All new compounds were characterised by multinuclear NMR and X-ray diffraction.

引用

页码：6946 / 6949

页数：4

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