A quantitative study of carbon monoxide and carbon dioxide evolution during thermal degradation of flame retarded epoxy resins

被引：57
作者：
Biswas, Bhaskar [1 ]
Kandola, Baljinder K. [1 ]
Horrocks, A. Richard [1 ]
Price, Dennis [1 ]
机构：
[1] Univ Bolton, Ctr Mat Res & Innovat, Bolton BL3 5AB, England
来源：
POLYMER DEGRADATION AND STABILITY | 2007年 / 92卷 / 05期
关键词：
epoxy resin; flame retardants; TGA; EGA; carbon dioxide; carbon monoxide;
D O I：
10.1016/j.polymdegradstab.2007.02.006
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Thermogravimetric analysis (TGA) combined with infrared analysis of the evolved gases analysis (EGA) has been used to study the thermal degradation behaviour of epoxy resin both in air and nitrogen. The mass loss as a function of temperature has been correlated with the evolution of carbon monoxide (CO) and carbon dioxide (CO2), and oxygen consumption as measured using an oxygen analyser. An analytical technique has been developed to quantitatively measure the carbon monoxide and dioxide gases evolved. The effect of a range of flame retardants containing phosphorus, nitrogen and halogen elements on CO and CO2 evolution during thermal degradation of flame retarded epoxy resins has also been observed. (C) 2007 Elsevier Ltd. All rights reserved.
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页码：765 / 776
页数：12
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