A quantitative study of carbon monoxide and carbon dioxide evolution during thermal degradation of flame retarded epoxy resins

被引：59

作者：

Biswas, Bhaskar ^{[1
]}

Kandola, Baljinder K. ^{[1
]}

Horrocks, A. Richard ^{[1
]}

Price, Dennis ^{[1
]}

机构：

[1] Univ Bolton, Ctr Mat Res & Innovat, Bolton BL3 5AB, England

来源：

POLYMER DEGRADATION AND STABILITY | 2007年 / 92卷 / 05期

关键词：

epoxy resin; flame retardants; TGA; EGA; carbon dioxide; carbon monoxide;

D O I：

10.1016/j.polymdegradstab.2007.02.006

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Thermogravimetric analysis (TGA) combined with infrared analysis of the evolved gases analysis (EGA) has been used to study the thermal degradation behaviour of epoxy resin both in air and nitrogen. The mass loss as a function of temperature has been correlated with the evolution of carbon monoxide (CO) and carbon dioxide (CO2), and oxygen consumption as measured using an oxygen analyser. An analytical technique has been developed to quantitatively measure the carbon monoxide and dioxide gases evolved. The effect of a range of flame retardants containing phosphorus, nitrogen and halogen elements on CO and CO2 evolution during thermal degradation of flame retarded epoxy resins has also been observed. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：765 / 776

页数：12

共 39 条

[1]

[Anonymous], 1999, 45892 BS EN ISO

[2]

[Anonymous], 27821 BS ISO

[3]

[Anonymous], ACS S SERIES

[4]

[Anonymous], 1993, 476151993 BS

[5] The effect of a curing agent on the thermal degradation of fire retardant brominated epoxy resins [J].

Balabanovich, AI ;

Hornung, A ;

Merz, D ;

Seffert, H .

POLYMER DEGRADATION AND STABILITY, 2004, 85 (01) :713-723

[6]

BISWAS B, 2007, 11 EUR M FIR RET POL

[7] MECHANISTIC ASPECTS OF INTUMESCENT FIRE-RETARDANT SYSTEMS [J].

CAMINO, G ;

COSTA, L ;

LUDA, MP .

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1993, 74 :71-83

[8] Dynamic flame retardancy of polypropylene filled with ammonium polyphosphate, pentaerythritol and melamine additives [J].

Chiu, SH ;

Wang, WK .

POLYMER, 1998, 39 (10) :1951-1955

[9] ENHANCEMENT OF EVOLUTION PROFILES IN PYROLYSIS EVOLVED GAS INFRARED-SPECTROSCOPY OF POLYMERS [J].

DAVIDSON, RG .

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1989, 16 (02) :143-152

[10] The effects of structure on the thermal degradation of polyester resins [J].

Evans, SJ ;

Haines, PJ ;

Skinner, GA .

THERMOCHIMICA ACTA, 1996, 278 :77-89

← 1 2 3 4 →