Diiodobis(1-methyl-1,3-imidazolium-2-thiolato-S)mercury(II)

被引：16
作者：
Pavlovic, G [1 ]
Popovic, Z [1 ]
Soldin, Z [1 ]
Matkovic-Calogovic, D [1 ]
机构：
[1] Univ Zagreb, Fac Sci, Dept Chem, Lab Gen & Inorgan Chem, Zagreb 10000, Croatia
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2000年 / 56卷
关键词：
D O I：
10.1107/S0108270100005825
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of 1-methyl-1,3-imidazole-2-thione (meimtH) with mercury(II) iodide in methanol in a 2:1 molar ratio resulted in the formation of single crystals of the title compound, [HgI2 (C4H6N2S)(2)]. The Hg atom is coordinated by two I [2.7809 (9) and 2.7999 (8) Angstrom] and two thione S atoms [2.520 (3) and 2.576 (3) Angstrom] with irregular tetrahedral coordination geometry. The NH groups of the imidazole ring take part in intra- and intermolecular hydrogen bonds with I atoms [N ... I 3.596 (8) and 3.611 (9) Angstrom, respectively] joining molecules into infinite chains parallel to the z axis.
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页码：801 / 803
页数：3
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