Cu-Mn bimetallic catalyst for Huisgen [3+2]-cycloaddition

被引：31

作者：

Yousuf, Syed Khalid ^{[1
]}

Mukherjee, Debaraj ^{[1
]}

Singh, Baldev ^{[2
]}

Maity, Sudip ^{[3
]}

Taneja, Subhash Chandra ^{[1
]}

机构：

[1] Indian Inst Integrat Med CSIR, Bioorgan Chem Div, Jammu 180001, India

[2] Indian Inst Integrat Med CSIR, Catalyst Discipline, Jammu 180001, India

[3] CMFIR, Dhanbad, Jharkhand, India

来源：

GREEN CHEMISTRY | 2010年 / 12卷 / 09期

关键词：

GAS-SHIFT REACTION; CLICK CHEMISTRY; 1,3-DIPOLAR CYCLOADDITION; TERMINAL ALKYNES; REGIOSELECTIVE SYNTHESIS; HETEROGENEOUS CATALYST; OXIDE CATALYSTS; ONE-POT; AZIDES; WATER;

D O I：

10.1039/c005088a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cu-Mn spinel oxide catalyst has been investigated for the ligand-free Huisgen [3+2] cycloaddition. The copper( I) species required in the cycloaddition reaction has been stabilized in the tetrahedral site of the spinel without the need of a stabilizing agent. The new catalyst is robust and can be reused several times under MW conditions with negligible loss in catalytic activity.

引用

页码：1568 / 1572

页数：5

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