Reactivity of Fe3(CO)9(μ3-C2Et2).: Synthesis and structures of Fe2(CO)6{C2Et2C[CH2N(Me)CH2Ph]CH} and Fe3(CO)8{C2Et2C(H)C[CH2N(Me)CH2Ph]}

被引：9

作者：

Calderon, R

Vahrenkamp, H

机构：

[1] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany

[2] Univ Los Andes, Dept Quim, Merida 5101, Venezuela

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 555卷 / 01期

关键词：

propargylamine; ligand; ferracyclopentadiene ring;

D O I：

10.1016/S0022-328X(97)00719-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compounds Fe-2(CO)(6){C2Et2C[CH2N(Me)CH2Ph]CH} (3) and Fe-3(CO)(8){C2Et2C(H)C-[CH2N(Me)CH2Ph]} (4) resulted from the reaction of Fe-3(CO)(9)(mu(3)-eta(2)-perpendicular to-C2Et2) (1) with the substituted propargylamine N-benzyl-M-methylpropargylamine. Complexes 3 and 4 were characterized by X-ray structural determinations. Complexes 3 and 4 represent two orientations of insertion of the propargylamine between iron and the alkyne ligand of 1. The characteristic feature in both structures is the presence of a ferracyclopentadiene ring. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：113 / 118

页数：6

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