Highly efficient photocatalytic oxidation of C-H bond based on microchannel reactor

被引:3
作者
Li, Chuang [1 ]
Xu, Rong [1 ]
Song, Qingming [1 ]
Mao, Zhipeng [1 ]
Li, Junfeng [1 ]
Yang, Hongjun [1 ]
Chen, Jian [1 ]
机构
[1] Wuhan Univ Technol, Sch Chem, Chem Engn & Life Sci, Wuhan 430070, Peoples R China
关键词
Metal-free catalyst; 2-Methylanthraquinone; Microchannel reactor; Efficient oxidation; Aromatic ketones; Introduction; SELECTIVE OXIDATION; LIGHT; ACTIVATION; CATALYST; KETONES; OXYGEN;
D O I
10.1016/j.tetlet.2022.153818
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A mild photocatalytic C-H bond selective oxidation mediated by metal-free photocatalyst 2-Methylanthraquinone was reported. Glass microchannel reactor can enhance the absorption of photon energy and oxygen by the reaction mixture, so as to greatly improve the reaction efficiency of photocatalytic reaction in glass microchannel reactor. This reaction method can quickly oxidize alkyl aromatics into corresponding oxidation products to obtain aromatic ketones in high yield. CO 2022 Elsevier Ltd. All rights reserved.
引用
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页数:5
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