Hypervalent iodine(V) reagents in organic synthesis

被引：209
作者：
Ladziata, Uladzimir [1 ]
Zhdankin, Viktor V. [1 ]
机构：
[1] Univ Minnesota, Dept Chem & Biochem, Duluth, MN 55812 USA
来源：
ARKIVOC | 2006年
关键词：
hypervalent iodine; oxidation; iodylbenzene; IBX; DMP;
D O I：
10.3998/ark.5550190.0007.903
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This review summarizes the synthetic applications of hypervalent iodine(V) reagents: iodylbenzene, IBX (2-iodoxybenzoic acid), DMP (Dess-Martin periodinane) and pseudocyclic IBX analogs. Application of these reagents allows mild and highly selective oxidative transformations in a facile and environmentally friendly manner.
引用
收藏
页码：26 / 58
页数：33
相关论文
共 159 条
[1]   SECONDARY BONDING .6. DISTORTED OCTAHEDRAL GEOMETRY IN SELENINYL DICHLORIDE-DIOXAN (1-1) AND IODYLBENZENE [J].
ALCOCK, NW ;
SAWYER, JF .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (01) :115-120
[2]   OXIDATION OF SULFIDES BY IODYLARENES IN THE PRESENCE OF VANADYL ACETYLACETONATE AS A CATALYST [J].
BARRET, R ;
PAUTET, F ;
BORDAT, P ;
TINLAND, B ;
DAUDON, M .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1989, 45 (1-2) :31-33
[3]   SYNTHESIS OF QUINONE-IMINES WITH IODOXYBENZENE [J].
BARRET, R ;
DAUDON, M .
SYNTHETIC COMMUNICATIONS, 1990, 20 (10) :1543-1549
[4]  
Barret R., 1989, OXID COMMUN, V12, P55
[5]   OXIDATION OF OLEFINS WITH 2-PYRIDINESELENINIC ANHYDRIDE [J].
BARTON, DHR ;
CRICH, D .
TETRAHEDRON, 1985, 41 (19) :4359-4364
[6]   Flexible and convergent total synthesis of cyclotheonamide B [J].
Bastiaans, HMM ;
vanderBaan, JL ;
Ottenheijm, HCJ .
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (12) :3880-3889
[7]  
Boeckman R.K., 2000, J ORG SYN, V77, P141, DOI 10.15227/orgsyn.077.0141
[8]   Development of a novel silyl ether linker for solid-phase organic synthesis [J].
Boehm, TL ;
Showalter, HDH .
JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (19) :6498-6499
[9]   Stereoselective synthesis of the antifungal GM222712 [J].
Bueno, JM ;
Coterón, JM ;
Chiara, JL ;
Fernández-Mayoralas, A ;
Fiandor, JM ;
Valle, N .
TETRAHEDRON LETTERS, 2000, 41 (22) :4379-4382
[10]  
Chaudhari SS, 2000, SYNLETT, P278
12345678910