IRMOF-3 Functionalized GO/CuFe2O4: A New and Recyclable Catalyst for the Synthesis of Dihydropyrano[2,3-c]Pyrazoles under Ultrasound Irradiations

被引：17
作者：
Ghasemzadeh, Mohammad Ali [1 ]
Mirhosseini-Eshkevari, Boshra [1 ]
Dadashi, Jaber [2 ]
机构：
[1] Islamic Azad Univ, Qom Branch, Dept Chem, Post Box 37491-13191, Qom, Iran
[2] Iran Univ Sci & Technol, Dept Chem, Catalysts & Organ Synth Res Lab, Tehran 1684613114, Iran
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2022年 / 1261卷
关键词：
Heterogeneous Catalyst; Multi-Component Reactions; Metal-Organic Framework; Pyrano[2; 3-c]Pyrazole; GRAPHENE OXIDE; GREEN SYNTHESIS; ONE-POT; EFFICIENT; NANOPARTICLES; PYRAZOLE;
D O I：
10.1016/j.molstruc.2022.132843
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In the present study, we reported a facile and cost-effective method for synthesizing magnetic copper ferrite nanoparticles supported on IRMOF-3/GO [IRMOF-3/GO/CuFe2O4]. The prepared IRMOF-3/GO/CuFe2O4 was completely characterized by various spectroscopic techniques such as Brunauer-Emmett-Teller (BET), scanning electron microscopy (SEM), X-ray diffraction (XRD), infrared spectroscopy (IR), thermogravimetric (TGA), energy-dispersive X-ray spectroscopy, and elemental meapping. The synthesized nanocatalyst demonstrated high catalytic activity in the synthesis of dihydropyrano[2,3-c]pyrazoles via a one-pot reaction of hydrazine hydrate, acetylene ester, aryl aldehydes, and malononitrile exposed to ultrasound irradiations. In comparison to formerly reported approaches, this protocol has various advantages including wide substrate compatibility, short reaction times, excellent yields, little catalyst loading, good reusability, and high efficiency. The catalyst was separated by simple filtration and after several rounds of reuse and recovery, the amount of activity in this catalytic system remained nearly constant.(c) 2022 Elsevier B.V. All rights reserved.
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页数：11
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共 45 条
  • [1] MIL-53(Fe): Introduction of a new catalyst for the synthesis of Pyrimido[4,5-d]pyrimidine derivatives under solvent-free conditions
    Abdollahi-Basir, Mohammad Hossein
    Shirini, Farhad
    Tajik, Hassan
    Ghasemzadeh, Mohammad Ali
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2019, 1197 : 318 - 325
  • [2] Development of some magnetic metal-organic framework nano composites for pharmaceutical applications
    Abu-Dief, Ahmed M.
    Alrashedee, Fedaa M. M. M.
    Emran, Khadijah A.
    Al-Abdulkarim, Hessah
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2022, 138
  • [3] Magnetic NiFe2O4 nanoparticles: efficient, heterogeneous and reusable catalyst for synthesis of acetylferrocene chalcones and their anti-tumour activity
    Abu-Dief, Ahmed M.
    Nassar, Ibrahim F.
    Elsayed, Wafaa H.
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2016, 30 (11) : 917 - 923
  • [4] Chemically crosslinked isoreticular metal-organic frameworks
    Allen, Corinne A.
    Boissonnault, Jake A.
    Cirera, Jordi
    Gulland, Ryan
    Paesani, Francesco
    Cohen, Seth M.
    [J]. CHEMICAL COMMUNICATIONS, 2013, 49 (31) : 3200 - 3202
  • [5] A green and efficient protocol for the synthesis of dihydropyrano[2,3-c]pyrazole derivatives via a one-pot, four component reaction by grinding method
    Ambethkar, Sethurajan
    Padmini, Vediappen
    Bhuvanesh, Nattamai
    [J]. JOURNAL OF ADVANCED RESEARCH, 2015, 6 (06) : 975 - 985
  • [6] Four component synthesis of highly functionalized pyrano [2,3-c] pyrazoles from benzyl halides
    Beerappa, Mallappa
    Shivashankar, Kalegowda
    [J]. SYNTHETIC COMMUNICATIONS, 2018, 48 (02) : 146 - 154
  • [7] Immobilization of Pd(II) on MOFs as a highly active heterogeneous catalyst for Suzuki-Miyaura and Ullmann-type coupling reactions
    Chen, Liyu
    Gao, Zhiqiang
    Li, Yingwei
    [J]. CATALYSIS TODAY, 2015, 245 : 122 - 128
  • [8] Immobilizing Highly Catalytically Active Noble Metal Nanoparticles on Reduced Graphene Oxide: A Non-Noble Metal Sacrificial Approach
    Chen, Yao
    Zhu, Qi-Long
    Tsumori, Nobuko
    Xu, Qiang
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (01) : 106 - 109
  • [9] Ultrasound-Assisted Synthesis and DFT Calculations of the Novel 1D Pb (II) Coordination Polymer with Thiosemicarbazone Derivative Ligand and Its Use for Preparation of PbO Clusters
    Dadashi, Jaber
    Hanifehpour, Younes
    Mirtamizdoust, Babak
    Abdolmaleki, Mehdi
    Jegarkandi, Elham Mohammadi
    Rezaei, Mahboubeh
    Joo, Sang Woo
    [J]. CRYSTALS, 2021, 11 (06):
  • [10] Dehkordi R.B., 2020, J MOL STRUCT, V1206
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